You would need a thermometer, when it hits 80 degrees is when it brings up some concern. But on a residential job, there's no definitive way to tell the integrity of your concrete since you have no special inspectors around. There's several other factors which will affect your concrete other than temperature; slump, w/c ratio, mix design, consolidation, time on tickets, proper placement, properly adding water, control joints, reinforcement, air entrainment, proper curing.
If you're ever concerned about a pour, you can always hire special inspectors to monitor your pour for you. I used to work as one, and we would get a residential job every now and then where they hired us to check the pour even though they weren't required to.
When the concrete gets old before it even comes out of the chute. Usually the three hour mark is where we draw the line. As an inspector, if I saw that someone was about to pour three hour old concrete I would tell them "It's your concrete, use it if you want but if you do I have to make cylinders and test this, if they don't meet the minimum compressive strength then you will be liable". I test the concrete, I do it very well, is the message I try and get across, then I leave it on them.