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I use a tankless gas water heater to heat my spa. Works fine.
You want to do something completely different, may not work. Making this a zone on an existing heating system will result in mixing of the spa and heating water. I don't know if that will screw with your system or not. If that works for you, the next issue is pressure. If the heating system is a pressurized system, I don't think you can make this work because the spa is obviously non-pressurized.
The spa pump will pump far more than you can put through the boiler. That means you can only pump some of the water through the boiler then mix that back into the return water stream. Getting this set right is a challenge. You must provide adequate flow and pressure to fire the boiler without over-restricting the flow from the spa pump. In your case, you will be dealing with both the spa pump and the circulating pump so it will be even more difficult.
As for the control for the zone valve, that is pretty easy. You can get a bulb type sensor on a thermostat. The sensor inserts into the pipe through a threaded fitting, generally in a "T". That would open the zone valve and turn on the circulation pump for the heating system.
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