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It is prefered to let the concrete cure for at least 28 days. If there are curing agents used, you can get on sooner. You can check out the Society for Protective Coatings SSPC-PA 7 Specification for Applying Thin Film Coatings to Concrete for further information. Also check out the ACI International Standards for more standards available. Also, as far as test methods go, you can check out ASTM D4263. This the Plastic Sheet Test Method. This test only tells you the presence of moisture in the concrete. Pretty much ALL concrete has some moisture. For a detailed test, you will need a Quanative test to get the amount present. If the concrete is exposed on one side, then your not going to be trapping any moisture in place. It will have a way out, anyway. One thing is to make sure that you do the required surface prep. If you do not, then you can apply the best coating out there and it will not last. You can also check with the ICRI "International Concrete Repair Institute" for more information as well. There is a lot of information out there. Also, I would recommed to check with your coating supplier, to see what there requirements are for concrete application. Get a specification and follow it.
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