Depends on the time of year and the weather conditions....Most cordless batteries will be fine, but once it gets below freezing you will start to notice the performance suffer...
Li batteries are better in the cold the Nickle cadium, or nickle-metal hydride...
All batteries will discharge...Ni-cad Ni-MH will deplete faster than Li...It is not wise to leave your Nicads or Ni-MH on the carger 24-7 as they will charge to 100%...charger shuts off, they run down, Charge again..and so on and so on..Each time this happens it is 1 life cycle on the battery. The average Nicad NiMH gets about 450-600 charges, where as the Li gets around 2000.
Dewalt recommends that you leave there batteries on the charger, but at $80-90 a pop I am still not sure If i buy into that, or if they are just trying to sell more batteries..